{"id":35604,"date":"2023-08-28T13:00:34","date_gmt":"2023-08-28T13:00:34","guid":{"rendered":"https:\/\/entropymag.co\/?p=34701"},"modified":"2023-12-14T07:38:56","modified_gmt":"2023-12-14T02:08:56","slug":"the-role-of-the-aufbau-principle-in-modern-material-sciences-and-nanotechnology","status":"publish","type":"post","link":"https:\/\/entropymag.co\/the-role-of-the-aufbau-principle-in-modern-material-sciences-and-nanotechnology\/","title":{"rendered":"The Role of the Aufbau Principle in Modern Material Sciences and Nanotechnology"},"content":{"rendered":"\n

What is the Aufbau Principle? <\/h2>\n\n\n\n

The Aufbau Principle was formulated during the 1920s by Wolfgang Paul and Neil Bohrs. If we understand the semantics of the word “Aufbau” it means “building up” in German. The principle deals with various laws around the filling up of electronic orbitals. <\/p>\n\n\n\n

Atomic orbitals are of different types. Some orbitals are higher energy in nature and some are lower energy in nature. The Aufbau principle states that in a neutral state, the electrons are filled in a specific order wherein electrons always occupy the lowest energy levels. <\/p>\n\n\n\n

After all the available lower energy orbitals are filled the higher energy orbitals are filled. This helps us in providing a pattern around the process through which electrons are filled into atomic orbitals. <\/p>\n\n\n\n

Atomic orbitals<\/h3>\n\n\n\n

The Heisenberg Uncertainty Principle states that it’s improbable to understand an electron and determine its future course of action. However subsequent research around this domain has helped us understand the probable region where electrons exist. Thus we use atomic orbitals to understand the possible position of an electron around the nucleus m<\/p>\n\n\n\n

We already know that electrons revolve around the nucleus. However, these electrons exist in pairs and are located at various distances from the nucleus. Atomic orbitals help us gain insights into this phenomenon. The atomic orbitals of any atom are unique to themselves. <\/p>\n\n\n\n

They are considered to be the vast physical space around the nucleus. The mathematical functions associated with an atomic orbital help us understand the probable location where the electron might be present. <\/p>\n\n\n\n

Types of orbitals <\/h4>\n\n\n\n
\"Types<\/figure>\n\n\n\n

Atomic orbitals are classified into four types. Each type has its characteristics that influence the atom in general. The four types of orbitals are s\/p\/d\/f. Each orbital has a specific capacity for holding electrons. While the ‘s’ orbital holds two electrons other orbitals can hold a higher number of electrons. <\/p>\n\n\n\n

Capacity of orbitals<\/h4>\n\n\n\n

The ‘S’ orbital can occupy two electrons. The ‘P’ orbital possesses the  capacity to occupy six electrons. The ‘D’ orbital can accommodate a total of ten electrons. The ‘F’ orbital can occupy a total of fourteen electrons. <\/p>\n\n\n\n

Electronic configuration <\/h3>\n\n\n\n

The electronic configuration of an atom is dependent on the distribution of various electrons into the atomic orbitals. An atom\u2019s electronic configuration helps us understand the reactivity and interaction between elements. The goal of any element is to attain a stable electronic configuration. <\/p>\n\n\n\n

A stable electronic configuration is a situation wherein each atomic orbital is filled with the respective number of electrons. Therefore the reason for any reactivity within an element is due to unstable electronic configuration. The instability propels an atom to make or break bonds with other atoms. <\/p>\n\n\n\n

Understanding Orbitals <\/h3>\n\n\n\n

Electrons occupy orbitals around an atom. Each specific orbital possesses a specific energy level. Orbitals are of four types. Let’s understand these orbitals and their types. The orbitals determine the physical proximity to the nucleus of an atom. <\/p>\n\n\n\n

These orbitals are typically classified into s\/p\/d<\/em> and f<\/em>. However, each of these four levels is further divided into sub-levels. <\/p>\n\n\n\n

Aufbau Principle <\/h3>\n\n\n\n

The Aufbau Principle simply states that electrons start filling themselves starting from the lower energy levels and move forward to higher energy levels. This helps generate a systematic approach towards the filling of electrons wherein the filling process is directly dependent on the energy levels.  The electrons start filling the lower energy levels followed by their sublevels and thus keep progressing ultimately. The reason behind filling electrons based on relative energy can be attributed to the basic nature of an electron which focuses on always generating stability. <\/p>\n\n\n\n

The Aufbau principle provides us with the sequence through which electrons start filling around the orbitals. The sequence is as follows:<\/p>\n\n\n\n

1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s\u2026\u2026<\/em><\/p>\n\n\n\n

Understanding the sequence<\/h4>\n\n\n\n

The energy level ‘n=1’ is associated with the 1s orbital. Thus it always accommodates a total of 2 electrons. The energy level ‘n=2’ is associated with 2s and 2p electrons. The ‘s’ orbital has a capacity of two electrons while the ‘p’ orbital has a capacity of six electrons. <\/p>\n\n\n\n

Thus the level ‘n=2’ accommodates a total of eight electrons. The energy level ‘n=3’ is associated with a single ‘s’ orbital, three ‘p’ orbitals, and five ‘d’ orbitals. <\/p>\n\n\n\n

\"Aufbau
Source<\/a> | Aufbau Principle and material science <\/figcaption><\/figure>\n\n\n\n

This sequence dictates the filling order which can be understood according to the image sequence given above. The Aufbau principle directs this filling order. <\/p>\n\n\n\n

Let’s take an example to understand this in detail. A carbon atom has six electrons. These electrons will be filled in a specific manner. The first two electrons will occupy the ‘1s’ orbital which is closest to the nucleus. The next electrons will immediately occupy the ‘2s’ orbitals. The remaining electrons will try to integrate themselves in the ‘3s’ energy level. The ‘3s’ energy level needs six electrons to stabilize itself but it’s only filled with two electrons. Therefore carbon always tries to form bonds and attain stability either by donating its two electrons or trying to take four electrons from other atoms.  <\/p>\n\n\n\n

How Material Sciences Used the Aufbau Principle <\/h2>\n\n\n\n

Material science deals with elements and atoms. The properties of any atom or element directly depend on the electrons which influence the nature and reactivity of any atom. Even the internal arrangements of electrons within any atom is of paramount importance to understanding the characteristics of any atom. <\/p>\n\n\n\n

The Aufbau rule directly provides principles that can help predict various features of any atom. Some of its uses are as follows:<\/p>\n\n\n\n

Elemental Properties <\/h3>\n\n\n\n

The electronic configuration of any atom can be determined with the help of the Aufbau Principle. The principle gives us a direct process that can help in predicting the electronic configuration of any atom by taking into account its atomic number. The understanding of the atomic number helps in understanding the chemical nature and reactivity of any atom. <\/p>\n\n\n\n